Angewandte Chemie International Edition · 2017 · 72 citations · 53 references
Natural SciencesChemistryCatalysisOrganic ChemistryChemical BondingCross-coupling ReactionsReaction MechanismsC - C Coupling CatalysisCross-coupling CatalysisOxidative CatalysisOxidative Cross-couplingScopeSelectivityStereoselective Cross-couplingTransition-metal-catalyzed Functionalization
Abstract The silver‐catalyzed oxidative C(sp 3 )−H/P−H cross‐coupling of 1,3‐dicarbonyl compounds with H‐phosphonates, followed by a chemo‐ and regioselective C(sp 3 )−C(CO) bond‐cleavage step, provided heavily functionalized β‐ketophosphonates. This novel method based on a readily available reaction system exhibits wide scope, high functional‐group tolerance, and exclusive selectivity.
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Tobias Seiser, Tanguy Saget, Duc N. Tran et al. · Angewandte Chemie International Edition · 2011 · 590 citations · Full text
Metal-catalysed cleavage of carbon–carbon bonds
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Pd(II)-Catalyzed Phosphorylation of Aryl C–H Bonds
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