Simple, ultra-rapid, versatile method to synthesize cobalt/cobalt oxide nanostructures on carbon fiber paper via intense pulsed white light (IPWL) photothermal reduction for energy storage applications

Abstract

Cobalt-based nanomaterials have received considerable attention in electric energy-storage devices due to their outstanding electrochemical characteristics. However, multiple time- and energy-consuming steps and complex reduction processes for producing cobalt and cobalt oxide nanostructures are disrupting their substantive commercialization. Here, we propose a facile, ultra-fast, and versatile method for the fabrication of cobalt and cobalt oxide nanostructures using an intense pulsed white light (IPWL) photothermal reduction technique. The mechanism of the IPWL photothermal reduction of cobalt and cobalt oxide is firstly studied by measuring the in-situ temperature of the Co(NO 3 ) 2 -coated carbon fiber paper (CFP) substrate during IPWL irradiation and analyzing the crystal structures of the IPWL-irradiated samples. Cobalt nanoflakes and cobalt oxide nanoparticles are synthesized on the surface of the CFP substrate by irradiating IPWL for 10 ms at ambient temperature and pressure with various energy densities from 10 to 30 J cm −2 . The Co 3 O 4 nanoparticle/CFP and Co nanoflake/CFP samples are further utilized as an electrode, and each electrode exhibits high specific capacity of 29 and 73 mA h g −1 , respectively, at a current density of 1 A g −1 . Since this novel photothermal reduction technique is applicable to other transition metals and metal oxides , it is a promising method for not only energy storage systems , but also for energy generation applications, filters, sensors, and catalysis systems. The intense pulsed white light (IPWL) photothermal reduction process enables ultra-rapid and facile synthesis of cobalt nanoflakes and cobalt oxide nanoparticles on carbon fiber paper (CFP). The IPWL-induced Co 3 O 4 nanoparticle/CFP and Co nanoflake/CFP electrodes exhibit high specific capacity, as well as excellent rate capability and cycle stability. • Facile, ultra-fast, versatile IPWL photothermal reduction technique is proposed. • Co nanoflakes and cobalt oxide nanoparticles are fabricate on CFP by IPWL. • The mechanism of the IPWL photothermal reduction of cobalt/cobalt oxide is studied.