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Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy<sub>2</sub>ScN@C<sub>80</sub>-I<sub>h</sub>

DOIFull Paper Access

109

Citations

44

References

2017

Year

D. S. Krylov, Fupin Liu, Stanislav M. Avdoshenko, Lukas Spree, Bruno Weise, Anja Waske, A. U. B. Wolter, B. Büchner, Alexey A. Popov
Chemical Communications

Abstract

The Dy-Sc nitride clusterfullerene Dy<sub>2</sub>ScN@C<sub>80</sub>-I<sub>h</sub> exhibits slow relaxation of magnetization up to 76 K. Above 60 K, thermally-activated relaxation proceeds via the fifth-excited Kramers doublet with the energy of 1735 ± 21 K, which is the highest barrier ever reported for dinuclear lanthanide single molecule magnets.

References

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