Ultra-bright and highly efficient inorganic based perovskite light-emitting diodes

TLDR

Inorganic perovskites such as CsPbX₃ (X = Cl, Br, I) are prized for their thermal stability and high photoluminescence quantum efficiency. The study aimed to improve the electroluminescence efficiency of CsPbBr₃ LEDs by mitigating leakage current, non‑radiative recombination, and charge imbalance. They incorporated a small amount of methylammonium into the CsPbBr₃ lattice and applied a hydrophilic, insulating polyvinylpyrrolidone layer on the ZnO electron‑injection layer to reduce leakage and recombination. The mixed‑cation perovskite LEDs achieved 91,000 cd m⁻² brightness and 10.4 % EQE, the highest reported for green perovskite LEDs.

Abstract

Abstract Inorganic perovskites such as CsPbX 3 (X=Cl, Br, I) have attracted attention due to their excellent thermal stability and high photoluminescence quantum efficiency. However, the electroluminescence quantum efficiency of their light-emitting diodes was <1%. We posited that this low efficiency was a result of high leakage current caused by poor perovskite morphology, high non-radiative recombination at interfaces and perovskite grain boundaries, and also charge injection imbalance. Here, we incorporated a small amount of methylammonium organic cation into the CsPbBr 3 lattice and by depositing a hydrophilic and insulating polyvinyl pyrrolidine polymer atop the ZnO electron-injection layer to overcome these issues. As a result, we obtained light-emitting diodes exhibiting a high brightness of 91,000 cd m −2 and a high external quantum efficiency of 10.4% using a mixed-cation perovskite Cs 0.87 MA 0.13 PbBr 3 as the emitting layer. To the best of our knowledge, this is the brightest and most-efficient green perovskite light-emitting diodes reported to date.