Sorption studies of heavy metal ions on pectin-nano-titanium dioxide composite adsorbent

Abstract

The Cu(II), Cd(II), Zn(II), and Pb(II) sorption kinetics and equilibrium on hybrid material, composed of pectin and titanium dioxide nanopowder, were examined. Parameters, such as pH and adsorbent dose, were also investigated. The experimental data were better described by the Langmuir model. The maximum adsorption capacities were 1.37, 0.68, 0.51, and 0.83 mmol/g for Cu(II), Cd(II), Zn(II), and Pb(II), respectively. The introduction of nano-TiO2 improved the kinetics of the metal ion sorption. The titanium dioxide, despite its small content (6%), contributes to the removal of the examined metal ions and eventually to the adsorption capacity of hybrid beads.