Superacids Based on Pentafluoroorthotellurate Derivatives of Aluminum

Abstract

The new Lewis acid Al(OTeF₅ )₃ and its acetonitrile adduct CH₃ CN→Al(OTeF₅ )₃ were obtained by a simple one-step synthesis in batches of up to 15 g. Al(OTeF₅ )₃ and the adduct were characterized by vibrational spectroscopy (IR, Raman) and quantum-chemical calculations. Furthermore, five different salts of the new weakly coordinating anion [Al(OTeF₅ )₄ ]^- were prepared in a two-step procedure. [Ph₄ P][Al(OTeF₅ )₄ ], Cs[Al(OTeF₅ )₄ ], [Ph₃ C][Al(OTeF₅ )₄ ], as well as the protonated benzene derivatives [C₉ H₁₃ ][Al(OTeF₅ )₄ ] and [C₆ H₇ ][Al(OTeF₅ )₄ ] were characterized by low-temperature single-crystal X-ray diffraction and NMR spectroscopy. Arenium salts have rarely been characterized in the solid state and were synthesized in this work in a simplified fashion.