Chemiluminescence detection of trace iodide with flow injection analysis of KMnO₄‐carbon dots system

Abstract

Ultra-weak chemiluminescence (CL) from the reaction of iodide and KMnO₄ was strongly enhanced by carbon nanodots (CNDs) in an acidic medium. The CL intensity was directly proportional to the concentration of iodide in the solution. Therefore, a flow-injection CL system with high sensitivity, selectivity and reproducibility is proposed for the determination of iodide. The proposed method exhibited advantages over a linear range of 3.0 × 10^-6 -1.0 × 10^-4 mol/L and had a detection limit of 3.5 × 10^-7 mol/L. The method was successfully applied to the evaluation of iodide in food samples with recoveries of between 96 and 103%. The relative standard deviations were 2.1 and 4.1% for intra- and inter-assay precision, respectively.