First reprocessing of Southern Hemisphere ADditional OZonesondes (SHADOZ) profile records (1998–2015): 1. Methodology and evaluation

Abstract

Abstract Electrochemical concentration cell ozonesonde measurements are an important source of highly resolved vertical profiles of ozone (O 3 ) with long‐term data records for deriving O 3 trends, model development, satellite validation, and air quality studies. Ozonesonde stations employ a range of operational and data processing procedures, metadata reporting, and instrument changes that have resulted in inhomogeneities within individual station data records. A major milestone is the first reprocessing of seven Southern Hemisphere ADditional OZonesondes (SHADOZ) station ozonesonde records to account for errors and biases in operating/processing procedures. Ascension Island, Hanoi, Irene, Kuala Lumpur, La Réunion, Natal, and Watukosek station records all show an overall increase in O 3 after reprocessing. Watukosek shows the largest increase of 9.0 ± 2.1 Dobson Units (DU) in total column O 3 ; Irene and Hanoi show a 5.5 ± 2.5 DU increase, while remaining sites show statistically insignificant enhancements. Negligible to modest O 3 enhancements are observed after reprocessing in the troposphere (up to 8%) and stratosphere (up to 6%), except at La Réunion for which the application of background currents reduces tropospheric O 3 (−2.1 ± 1.3 DU). Inhomogeneities due to ozonesonde/solution‐type changes at Ascension, Natal, and La Réunion are resolved with the application of transfer functions. Comparisons with EP‐TOMS, Aura's Ozone Monitoring Instrument and Microwave Limb Sounder (MLS) satellite O 3 overpasses show an overall improvement in agreement after reprocessing. Most reprocessed data sets show a significant reduction in biases with MLS at the ozone maximum region (50–10 hPa). Changes in radiosonde/ozonesonde system and nonstandard solution types can account for remaining discrepancies observed at several sites when compared to satellites.