Concepedia

N-Heterocyclic carbene-stabilised arsinidene (AsH)

Adinarayana Doddi, Michael A. K. Weinhart, Alexander Hinz, Dirk Bockfeld, José M. Goicoechea, Manfred Scheer, Matthias Tamm

Chemical Communications · 2017 · 72 citations · 39 references

DOI

Concepts

Abstract

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe<sub>3</sub>)<sub>3</sub> with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)<sub>3.31</sub>][AsCO] with imidazolium chlorides.

References

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