Concepedia

N,N-Dimethylformamide-stabilized copper nanoparticles as a catalyst precursor for Sonogashira–Hagihara cross coupling

Hideo Oka, Katsuya Kitai, Takeyuki Suzuki, Yasushi Obora

RSC Advances · 2017 · 38 citations · 49 references

DOIFull text

Open access

Concepts

Abstract

We found that DMF-stabilized Cu NPs have high catalytic activity in the Sonogashira cross-coupling reaction at low catalyst loadings (0.2 mol%).

References

49

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

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Acetylenic Coupling: A Powerful Tool in Molecular Construction

Peter Siemsen, R. C. Livingston, François Diederich · Angewandte Chemie International Edition · 2000 · 1.5K citations

, , +12

Effect of Catalysis on the Stability of Metallic Nanoparticles:  Suzuki Reaction Catalyzed by PVP-Palladium Nanoparticles

Radha Narayanan, Mostafa A. El‐Sayed · Journal of the American Chemical Society · 2003 · 771 citations

, , +17

Shape Evolution and Size-Controllable Synthesis of Cu<sub>2</sub>O Octahedra and Their Morphology-Dependent Photocatalytic Properties

Haolan Xu, Wenzhong Wang, Wei Zhu · The Journal of Physical Chemistry B · 2006 · 541 citations

, , +17

Copper-Catalyzed Suzuki Cross-Coupling Using Mixed Nanocluster Catalysts

Mehul B. Thathagar, Jurriaan Beckers, Gadi Rothenberg · Journal of the American Chemical Society · 2002 · 301 citations

, , +17