Low-temperature activation of methane on the IrO ₂ (110) surface

Abstract

Low-temperature methane reactions Methane is a potential feedstock for more valuable products. The strong carbon-hydrogen bonds of methane can be activated by heterogeneous catalysts but often at temperatures that make it difficult to control reactions selectively. Liang et al. show that methane, adsorbed on the stoichiometric IrO 2 (110) under ultrahigh-vacuum conditions, reacts with exposed iridium atoms to break the carbon-hydrogen bonds at temperatures as low as 150 K. On heating, the surface fragments react cleanly with surface oxygen to form carbon dioxide, carbon monoxide, and water. Science , this issue p. 299