Organic & Biomolecular Chemistry · 2017 · 16 citations · 50 references
Natural SciencesChemical EngineeringChemistryCatalysisOrganic ChemistryReaction EngineeringCatalyst DesignCatalyst PreparationCatalytic MaterialsCatalytic Reaction EngineeringCross-coupling ReactionsHeterocyclic ChemistryCatalyst Structure - Activity RelationshipsCatalyst Structure-activity RelationshipsCatalytic ActivityCatalytic Activity EnhancementCross-coupling CatalysisPalladium CatalystsPalladium-catalyzed Cross-couplingSuzuki - Miyaura Coupling
An easily available Pd(OAc)2/(2-(anthracen-9-yl)-1H-inden-3-yl) dicyclohexylphosphine/toluene/iPrOH/water catalytic system was developed, which shows high catalytic activity in the Suzuki–Miyaura cross-coupling reactions of a diverse array of aryl and heteroaryl chlorides with Pd loadings down to 0.01 mol%.
50