Multiple shape memory effects of <i>trans</i>‐1,4‐polyisoprene and low‐density polyethylene blends

Abstract

Abstract A novel series of shape memory blends of trans ‐1,4‐polyisoprene ( TPI ) and low‐density polyethylene ( LDPE ) were prepared using a simple physical blending method. The mechanical, thermal and shape memory properties of the blends were studied and schemes proposed to explain their dual and triple shape memory behaviors. It was found that the microstructures played an important role in the shape memory process. In TPI / LDPE blends, both the TPI crosslinking network and LDPE crystalline regions could work as fixed domains, while crystalline regions of LDPE or TPI could act as reversible domains. The shape memory behaviors were determined by the components of the fixed and reversible domains. When the blend ratio of TPI / LDPE was 50/50, the blends showed excellent dual and triple shape memory properties with both high shape fixity ratio and shape recovery ratio. © 2017 Society of Chemical Industry