Synthesis of a Degradable High-Performance Epoxy-Ended Hyperbranched Polyester

Abstract

Degradation and recycling of cured thermosetting epoxy resins are major challenges to the industry. Here, a low-viscosity, degradable epoxy-ended hyperbranched polyester (DEHP) is synthesized by a reaction between epichlorohydrin and a carboxyl-ended hyperbranched polyester (DCHP) obtained from an esterification between citric acid and maleic anhydride. The chemical structures of DCHP and DEHP were characterized by Fourier transform infrared and ¹H NMR. DEHP has a positive effect on reinforcing and toughening of the diglycidyl ether of bisphenol-A (DGEBA). With an increase in the content and molecular weight of DEHP, the mechanical performances of the cured DEHP/DGEBA composites, including the tensile, flexural, and impact strengths, increase first and then decrease. The improvements on the tensile, flexural, and impact strengths were 34.2-43.4%, 35.6-48.1%, and 117.9-137.8%, respectively. Moreover, the DEHP also promotes degradation of the cured DEHP/DGEBA composites. The degree of degradation of the cured DEHP/DGEBA composites increases with an increase of the DEHP content and molecular weight. The composites containing 12 wt % DEHP can be degraded completely in only about 2 h at about 90 °C, compared with the degradation degree (35%) of cured DGEBA, indicating good degradation and recycling properties of the DEHP.