A highly stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixture

Abstract

Na₂(B₁₂H₁₂)_0.5(B₁₀H₁₀)_0.5, a new solid-state sodium electrolyte is shown to offer high Na⁺ conductivity of 0.9 mS cm^-1 at 20 °C, excellent thermal stability up to 300 °C, and a large electrochemical stability window of 3 V including stability towards sodium metal anodes, all essential prerequisites for a stable room-temperature 3 V all-solid-state sodium-ion battery.