Publication | Closed Access
First structural evidence of a Se–Br–Br halogen-bonded molecular complex
25
Citations
29
References
2017
Year
Inorganic ChemistryEngineeringBiochemistryStructural EvidenceNatural SciencesChemical BondCoordination ComplexOrganic ChemistryMolecular ComplexChemistryHalogenationBicyclic SelenoetherInorganic Synthesis
Bromination of the bicyclic selenoether (2,6-dibromo-9-selenabicyclo[3.3.1]-nonane) affords the products ranging from the unique molecular complex C<sub>8</sub>H<sub>12</sub>Br<sub>2</sub>Se–Br<sub>2</sub> to the ionic polybromide complex [C<sub>8</sub>H<sub>12</sub>Br<sub>2</sub>SeBr<sup>+</sup>]Br<sub>5</sub>.
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