Two copper(II) coordination polymers constructed by bis(4-(1<i>H</i>-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands

Abstract

Abstract Two new copper(II) complexes, {[Cu(bipmo)(npa)]} n ( 1 ) and {[Cu(bipmo)(pa)]} n ( 2 ) (bipmo=bis(4-(1 H -imidazol-1-yl)phenyl)methanone), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of neutral metal aromatic carboxylate layers, which are pillared by the weak interactions to generate 3D architectures. The topological structures of 1 and 2 are uninodal nets based on 4-connected nodes with the Schläfli symbol of (6 5 ·8).