Publication | Open Access
UV-light promoted C–H bond activation of benzene and fluorobenzenes by an iridium(<scp>i</scp>) pincer complex
12
Citations
28
References
2017
Year
Iridium(i) carbonyl complex [Ir(2,6-(P<sup>t</sup>Bu<sub>2</sub>CH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)(CO)] undergoes reversible C-H bond activation of benzene and a series of fluorobenzenes on UV irradiation. Exclusive ortho-selectivity is observed in reactions of fluorobenzene and 1,2-difluorobenzene.
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