Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride

Abstract

(1,3-bis[2,6-bis[di(4-tert-butylphenyl)methyl]-4-methylphenyl]imidazol-2-ylidene)CuOPh [(IPr**)CuOPh] reacts with poly(methylhydrosiloxane) as the hydride donor to afford the monomeric (IPr**)CuH complex, which was spectroscopically characterized. The latter is in equilibrium in solution with [(IPr**)CuH]₂ , the dimer being exclusively present in the solid state. These results support the hypothesis that copper hydride aggregates dissociate in solution. In contrast, addition of pinacolborane to [(IPr**)AgOPh] at -40 °C allows the isolation of the monomeric (IPr**)AgH complex, which was crystallographically characterized.