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Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel

Yusuke Aratani, Tomoyoshi Suenobu, Kei Ohkubo, Yusuke Yamada, Shunichi Fukuzumi

Chemical Communications · 2017 · 39 citations · 44 references

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Abstract

Hydrogen peroxide was produced from oxygen and water <italic>via</italic> visible-light irradiation of polymeric heteronuclear cyano-bridged complexes with the 2,2′-bipyridine ligand (bpy) (M<sup>II</sup>[Ru<sup>II</sup>(CN)<sub>4</sub>(bpy)]; M<sup>II</sup> = Ni<sup>II</sup>, Fe<sup>II</sup> and Mn<sup>II</sup>).

References

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