Formation and evolution of orientation-specific CO2 chains on nonpolar ZnO(1010) surfaces

Abstract

Abstract Clarifying the fundamental adsorption and diffusion process of CO 2 on single crystal ZnO surfaces is critical in understanding CO 2 activation and transformation over ZnO-based catalysts. By using ultrahigh vacuum-Fourier transform infrared spectroscopy (UHV-FTIRS), we observed the fine structures of CO 2 vibrational bands on ZnO(10"Equation missing"0) surfaces, which are the combinations of different vibrational frequencies, originated from CO 2 monomer, dimer, trimer and longer polymer chains along [0001] direction according to the density functional theory calculations. Such novel chain adsorption mode results from the relatively large attractive interaction between CO 2 and Zn 3c atoms in [0001] direction. Further experiments indicate that the short chains at low coverage evolve into long chains through Ostwald ripening by annealing. At higher CO 2 coverage (0.7 ML), the as-grown local (2 × 1) phase of chains first evolve into an unstable local (1 × 1) phase below 150 K, and then into a stable well-defined (2 × 1) phase above 150 K.