Assessing seawater intrusion in an arid coastal aquifer under high anthropogenic influence using major constituents, Sr and B isotopes in groundwater

Jürgen Mahlknecht, Daniel Merchán, Martin Rösner, Anette Meixner, Rogelio Ledesma‐Ruiz

The Science of The Total Environment · 2017 · 157 citations · 32 references

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Abstract

exchange occurring in sediments that were previously in chemical equilibrium with fresh water. However, seawater contribution was not sufficient to explain the observed concentrations and isotopic signatures of Sr and B. According to the isotopic data, desorption processes triggered by a modification in chemical equilibrium and an increase in ionic strength by seawater intrusion significantly increased Sr and probably B concentrations in groundwater. From a calculation of seawater contribution to the wells, it was estimated that one-third of the sampled abstraction wells were significantly affected by seawater intrusion, reaching concentrations that would limit their use for human supply or even irrigated agriculture. In addition, significant agricultural pollution (nitrates) was detected. Planned management of the aquifer and corrective measures are needed in order to invert the salinization process before it severely affects water resources in the long term.

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