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Redox control in palladium catalyzed norbornene and alkyne polymerization
40
Citations
53
References
2017
Year
Inorganic ChemistryChemical EngineeringCross-coupling ReactionEngineeringPalladium ComplexesRedox ControlSwitchable PolymerizationRedox-active Naphthoquinone MoietyOrganometallic CatalysisCatalysisChemistryPolymer ChemistryCatalytic Synthesis
Switchable polymerization of norbornene, 5-norbornene-2-yl acetate and 1-chloro-1-octyne could be realized by using two palladium complexes (NHC)Pd(allyl)Cl (NHC = 1,3-Ar<sub>2</sub>-naphthoquinimidazolylidene, Ar = 2,6-Me<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>, 2,6-<sup>i</sup>Pr<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>) bearing a redox-active naphthoquinone moiety.
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