Reversible Control of Interfacial Magnetism through Ionic-Liquid-Assisted Polarization Switching

Abstract

The ability to control magnetism of materials via electric field enables a myriad of technological innovations in information storage, sensing, and computing. We use ionic-liquid-assisted ferroelectric switching to demonstrate reversible modulation of interfacial magnetism in a multiferroic heterostructure composed of ferromagnetic (FM) La_0.8Sr_0.2MnO₃ and ferroelectric (FE) PbZr_0.2Ti_0.8O₃. It is shown that ionic liquids can be used to persistently and reversibly switch a large area of a FE film. This is a prerequisite for polarized neutron reflectometry (PNR) studies that are conducted to directly probe magnetoelectric coupling of the FE polarization to the interfacial magnetization.