Coordination Chemistry and Reactivity of Bis(aldimino)pyridine Nickel Complexes in Four Different Oxidation States

Abstract

A series of nickel complexes with potentially redox active bis(aldimino)pyridine ligands [NNN] ([NNN] = 1,1′-(pyridine-2,6-diyl)bis( N -arylmethanimine), where aryl = 2,6-diisopropylphenyl, mesityl, 4-methoxyphenyl, 4-trifluoromethylphenyl, and 3,5-bis(trifluoromethyl)phenyl) were synthesized, and their properties and reactivities were investigated as a function of the overall oxidation state of the system. (Ni[NNN]) 2+ complexes of ligands featuring bulky electron-rich substituents ( 1a-Br 2 and 1b-Br 2, [NNN] = 1,1′-(pyridine-2,6-diyl)bis( N -(2,6-diisopropylphenyl)methanimine) and 1,1′-(pyridine-2,6-diyl)bis( N -mesitylmethanimine), respectively) demonstrated five electrochemical reduction events, the first three of which were quasi-reversible. In contrast, only two quasi-reversible reductions were observed for the less bulky and electron-deficient N -aryl substituents 4-(trifluoromethyl)phenyl and 3,5-bis(trifluoromethyl)phenyl. Chemical reduction of 1a-Br 2 and 1b-Br 2 with 1 equiv of KC 8 or CoCp* 2 forms (Ni[NNN]) + complexes of the general formula Ni[NNN]Br ( 2a-Br and 2b-Br ). Structural, spectroscopic, and theoretical studies reveal that these complexes feature significant unpaired spin density on the metal, consistent with “nickel(I)” character. This behavior is in contrast with previously reported bis(ketimino)pyridine systems, in which at the (Ni[NNN]) + state the unpaired electron resided exclusively in the ligand. Further reduction forms a series of (Ni[NNN]) 0 complexes, in which all of the potentially tridentate [NNN] ligands bind via only one iminopyridine unit; the second arm is left unbound in most complexes. Variable temperature NMR spectroscopy demonstrates that bound and unbound arms exchange via a postulated tridentate intermediate. Electrochemical reduction, via three sequential one-electron reductions, of 1a-Br 2 and 1b-Br 2 in the presence of CO 2 /H + forms an active catalyst for H 2 evolution at a glassy-carbon electrode surface, again emphasizing the unique redox chemistry of the bulky bis(aldimino)pyridine nickel complexes.