Facile Synthesis of Carbon-Coated Spinel Li₄Ti₅O₁₂/Rutile-TiO₂ Composites as an Improved Anode Material in Full Lithium-Ion Batteries with LiFePO₄@N-Doped Carbon Cathode

Abstract

The spinel Li₄Ti₅O₁₂/rutile-TiO₂@carbon (LTO-RTO@C) composites were fabricated via a hydrothermal method combined with calcination treatment employing glucose as carbon source. The carbon coating layer and the in situ formed rutile-TiO₂ can effectively enhance the electric conductivity and provide quick Li⁺ diffusion pathways for Li₄Ti₅O₁₂. When used as an anode material for lithium-ion batteries, the rate capability and cycling stability of LTO-RTO@C composites were improved in comparison with those of pure Li₄Ti₅O₁₂ or Li₄Ti₅O₁₂/rutile-TiO₂. Moreover, the potential of approximately 1.8 V rechargeable full lithium-ion batteries has been achieved by utilizing an LTO-RTO@C anode and a LiFePO₄@N-doped carbon cathode.