ChemistrySelect · 2017 · 36 citations · 85 references
Room TemperatureChemical EngineeringEngineeringRemote C−h NitrationOrganic ChemistryOrganometallic CatalysisCatalysisChemistryEfficient CopperCatalytic Synthesis
Abstract A highly efficient copper catalyzed remote C−H nitration of 8‐amidoquinolines has been developed using tert ‐butyl nitrite as nitrating agent. 5 mol% of catalyst under room temperature furnished the products in excellent yields for arene, heteroarene, aliphatic carboxamide derivatives.
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Ligand-enabled meta-C–H activation using a transient mediator
Xiaochen Wang, Wei Gong, Lizhen Fang et al. · Nature · 2015 · 585 citations · Full text