Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

Abstract

A silver-catalyzed three-component reaction of diazoketones, anilines and NFSI is developed. The reaction provides a new method for <italic>gem</italic>-aminofluorination of acceptor diazo compounds with aniline as the nitrogen source and NFSI as the fluorine source.