Heteroleptic, two-coordinate [M(NHC){N(SiMe<sub>3</sub>)<sub>2</sub>}] (M = Co, Fe) complexes: synthesis, reactivity and magnetism rationalized by an unexpected metal oxidation state

Andreas A. Danopoulos, Pierre Braunstein, Kirill Yu. Monakhov, Jan van Leusen, Paul Kögerler, Martin Clémancey, Jean‐Marc Latour, Anass Benayad, Moniek Tromp, Elixabete Rezabal,

Dalton Transactions · 2016 · 35 citations · 69 references

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Abstract

Magnetism, XPS and XANES data of the title complexes imply M<sup>II</sup>centres coupled to one ligand-delocalized electron.

References

69