One-Step Hydrothermal Synthesis of W-Doped VO₂ (M) Nanorods with a Tunable Phase-Transition Temperature for Infrared Smart Windows

Abstract

Vanadium dioxide (VO₂), with reversible metal-semiconductor transition near room temperature, is a compelling candidate for thermochromic windows. Nanocomposite coatings derived from VO₂ nanoparticles are particularly superior to VO₂ films due to their advantages in large-scale preparation, flexible shaping, and regulation of optical properties. In this work, we developed a novel method for one-step hydrothermal synthesis of W-doped VO₂ (M) nanorods and studied their application in large-scale infrared smart windows. On introducing tartaric acid as a new reductant, VO₂ underwent a two-stage phase evolution from the pure phase comprising VO₂ (A) nanobelts to VO₂ (M) nanorods, instead of the conventional three-stage B-A-M phase evolution during hydrothermal synthesis. This transition is very favorable for the large-scale hydrothermal synthesis of VO₂ (M). The phase-transition temperature of VO₂ (M) nanoparticles can be regulated systematically by W doping, with a reduction efficiency of about 24.52 °C/atom % W. Moreover, VO₂ (M) composite films were fabricated using a convenient roller coating method, which exhibited significant midinfrared transmission switching up to 31%, with a phase-transition temperature of about 37.3 °C. This work demonstrates the significant progress in the one-step hydrothermal synthesis of VO₂ (M) nanorods and provides significant insights into their applications in infrared smart windows.