Site-selective Cp*Rh(<scp>iii</scp>)-catalyzed C–H amination of indolines with anthranils

Abstract

The pyrimidinyl-directed C–H functionalization of indolines with anthranils as amination sources under rhodium(<sc>iii</sc>) catalysis is described to afford a range of C7-aminated indoline derivatives with excellent site-selectivity and functional group compatibility.