Noble‐Metal‐Free Photocatalytic Hydrogen Evolution Activity: The Impact of Ball Milling Anatase Nanopowders with TiH₂

Abstract

Ball milling TiO₂ anatase together with TiH₂ can create an effective photocatalyst. The process changes the lattice and electronic structure of anatase. Lattice deformation created by mechanical impact combined with hydride incorporation yield electronic gap-states close to the conduction band of anatase. These provide longer lifetimes of photogenerated charge carriers and lead to an intrinsic cocatalytic activation of anatase for H₂ evolution.