Publication | Closed Access
Delineating The Multiple Roles of B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> in the Chemoselective Deoxygenation of Unsaturated Polyols
41
Citations
29
References
2016
Year
Single Versatile CatalystEngineeringOrganic ChemistryDeoxygenationChemistryChemical EngineeringChemoselective DeoxygenationOrganometallic CatalysisReaction IntermediateCross-coupling ReactionUnsaturated PolyolsDiversity-oriented SynthesisLewis Acid CyclizationReactivity (Chemistry)CatalysisAsymmetric CatalysisBiomolecular EngineeringAllylic Alcohol HydrosilylationNatural SciencesMultiple RolesSynthetic Chemistry
A set of B(C6F5)3-catalyzed methods for diversification of unsaturated carbohydrate derived substrates is disclosed. Lewis acid cyclization, allylic alcohol hydrosilylation, and selective silyl group exchange is achieved with this single versatile catalyst. Allylic polyols and highly enriched (Z)-triols are obtained in high yields under a single-step protocol.
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