Communication: Dopant-induced solvation of alkalis in liquid helium nanodroplets

Abstract

Alkali metal atoms and small alkali clusters are classic heliophobes and when in contact with liquid helium they reside in a dimple on the surface. Here we show that alkalis can be induced to submerge into liquid helium when a highly polarizable co-solute, C₆₀, is added to a helium nanodroplet. Evidence is presented that shows that all sodium clusters, and probably single Na atoms, enter the helium droplet in the presence of C₆₀. Even clusters of cesium, an extreme heliophobe, dissolve in liquid helium when C₆₀ is added. The sole exception is atomic Cs, which remains at the surface.