Publication | Closed Access
Total Synthesis of Hapalindole‐Type Natural Products
30
Citations
83
References
2014
Year
Diversity Oriented SynthesisEngineeringBiochemistryOxidative Cyclization StrategyNatural SciencesDiversity-oriented SynthesisTotal SynthesisOrganic ChemistryHapalonamide HChemistrySynthesis MethodHapalindoles HNatural Product SynthesisSynthetic ChemistryBiomolecular Engineering
Abstract A unified and bioinspired oxidative cyclization strategy was used in the first total syntheses of naturally occurring 12‐epi‐hapalindole Q isonitrile, hapalonamide H, deschloro 12‐epi‐fischerindole I nitrile, and deschloro 12‐epi‐fischerindole W nitrile, as well as the structural revision of the latter. Hapalindoles H and Q were also synthesized.
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