Organic Letters · 2016 · 16 citations · 19 references
EngineeringDriven Two-Synthetic PhotochemistryOrganic ChemistryChemistryHeterocycle ChemistryTbso GroupStereoselective PhotorearrangementNew Two-photon SequencePhotophysical PropertyPhotonicsPhotochemistryThree-photon Cascade ProcessesMechanistic PhotochemistryPhotonic MaterialsSupramolecular PhotochemistryPhotochromismBiomolecular EngineeringHeterocyclicApplied PhysicsTwo-photon Photocycloaddition/rearrangement
A TBSO group has been shown to exert a high degree of stereocontrol during the two-photon photocycloaddition/rearrangement of N-butenylpyrroles to complex tricyclic aziridines. Moreover, this and other bulky groups have been shown to change the outcome of the reaction, promoting a new two-photon sequence to tricyclic imines and an unprecedented stereoselective three-photon sequence to azabicyclo[3.3.1]nonanes.
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Catalytic enantioselective reactions driven by photoinduced electron transfer
Andreas Bauer, Felix Westkämper, Stefan Grimme et al. · Nature · 2005 · 479 citations