Effect of surface finishing on the formation of nanostructure and corrosion behavior of Ni–Ti alloy

Abstract

In the present work, we have investigated the formation of nanostructured oxide layers by anodic oxidation on different surface finished (mirror finished, 600 and 400 grit polished) nickel–titanium alloy (Ni–Ti) in electrolyte solution containing ethylene glycol and NH 4 F . The anodized surface has been characterized by field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS) and X‐ray photoelectron spectroscopy (XPS). The corrosion behaviors of the Ni–Ti substrate and anodized samples have been investigated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization in simulated body fluid (Hanks' solution). The results show that the native oxide on the substrate is replaced by nanostructures through anodization process. XPS of Ni–Ti substrate shows the presence of Ni 0 , NiO, Ti 0 and TiO 2 species, whereas Ni 2 O 3 and Ni(OH) 2 and TiO 2 are observed in the samples after anodization. Corrosion resistance of the anodized sample is comparable with that of the untreated sample. Copyright © 2016 John Wiley & Sons, Ltd.