Organocatalytic Vinyl Azide‐Carbonyl [3+2] Cycloaddition: High‐Yielding Synthesis of Fully Decorated <i>N</i>‐Vinyl‐1,2,3‐Triazoles

Abstract

Abstract For the first time, an enolate‐mediated organocatalytic vinyl azide‐carbonyl [3+2] cycloaddition (OrgVACC) of various ketones/aldehydes with vinyl azides is reported. It is an efficient intermolecular reaction with excellent outcomes with reference to rate, yield, selectivity, operational simplicity, substrate scope, catalyst simplicity, and vast applications.