Concepedia

Facile and selective hydrogenolysis of β-O-4 linkages in lignin catalyzed by Pd–Ni bimetallic nanoparticles supported on ZrO<sub>2</sub>

Jiawei Zhang, Yao Cai, Guoping Lu, Chun Cai

Green Chemistry · 2016 · 102 citations · 57 references

Concepts

Materials ScienceChemical EngineeringCatalytic Materialβ-O-4 LinkageSelective HydrogenolysisEngineeringLigninβ-O-4 LinkagesCatalysisHydrogenChemistryCatalyst PreparationCatalytic ProcessPd–ni Bimetallic NanoparticlesHydrogen GasLignin Chemistry

Abstract

The β-O-4 linkage in lignin can be selectively cleaved by Pd–Ni bimetallic nanoparticles supported on ZrO<sub>2</sub> using hydrogen gas as the hydrogen donor under ambient pressure and neutral conditions.

References

57

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Alireza Rahimi, Arne Ulbrich, Joshua J. Coon et al. · Nature · 2014 · 1.1K citations

Chemical Engineering, Polymer Chemistry, Engineering +7

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Engineering, Bioenergy, Lignin Conversion +17

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Alexey G. Sergeev, John F. Hartwig · Science · 2011 · 828 citations

Chemical Engineering, Biomass Conversion, Aryl Ethers +13

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Materials Science, Electron Density, Inorganic Chemistry +13

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