Using <i>o</i>‐Chlorobenzaldehyde as a Fast Removable Solvent Additive during Spin‐Coating PTB7‐Based Active Layers: High Efficiency Thick‐Film Polymer Solar Cells

Jin-Xiang Chen, Jin-Xiang Chen, Lianjie Zhang, Xiaofang Jiang, Ke Gao, Feng Liu, Xiangjun Gong, Junwu Chen, Junwu Chen, Yong Cao

Advanced Energy Materials · 2016 · 57 citations · 42 references

Concepts

Abstract

o-Chlorobenzaldehyde (CBA) is a derivative of chlorobenzene (CB). The boiling point of CBA is 212 °C, much lower than 332 °C for 1,8-diiodooctane (DIO). With CBA as solvent additive in CB host solvent, CBA could be fast removed during spin-coating 100, 200, and 300 nm thick thieno[3,4-b]thiophene/benzodithiophene polymer (PTB7):[6,6]-phenyl C71-butyric acid methyl ester (PC71BM) active layers, achieving power conversion efficiencies of 9.11%, 8.24%, and 7.11%, respectively, much higher than 7.53%, 5.71%, and 4.93% for corresponding DIO control devices with vacuum drying. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

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