Yolk–Shell Ni@SnO₂ Composites with a Designable Interspace To Improve the Electromagnetic Wave Absorption Properties

Abstract

In this study, yolk–shell Ni@SnO 2 composites with a designable interspace were successfully prepared by the simple acid etching hydrothermal method. The Ni@void@SnO 2 composites were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy. The results indicate that interspaces exist between the Ni cores and SnO 2 shells. Moreover, the void can be adjusted by controlling the hydrothermal reaction time. The unique yolk–shell Ni@void@SnO 2 composites show outstanding electromagnetic wave absorption properties. A minimum reflection loss (RL min ) of −50.2 dB was obtained at 17.4 GHz with absorber thickness of 1.5 mm. In addition, considering the absorber thickness, minimal reflection loss, and effective bandwidth, a novel method to judge the effective microwave absorption properties is proposed. On the basis of this method, the best microwave absorption properties were obtained with a 1.7 mm thick absorber layer (RL min = −29.7 dB, bandwidth of 4.8 GHz). The outstanding electromagnetic wave absorption properties stem from the unique yolk–shell structure. These yolk–shell structures can tune the dielectric properties of the Ni@air@SnO 2 composite to achieve good impedance matching. Moreover, the designable interspace can induce interfacial polarization, multiple reflections, and microwave plasma.