WO_3−xsensitized TiO₂spheres with full-spectrum-driven photocatalytic activities from UV to near infrared

Abstract

To make full use of solar energy for photocatalytic reactions, in this work, we developed full-spectrum-responsive photocatalysts with noteworthy photocatalytic activities under either UV, visible or even near infrared irradiation for the photodegradation of methylene blue. The core-shell structure of TiO₂@WO_3-x is designed from the consideration of combining the full-spectrum photo-absorption properties of WO_3-x with the excellent semiconductor properties of TiO₂. As expected, the WO_3-x sensitized TiO₂ sphere gives rise to a prominently strong optical absorption in the whole region of 300-2500 nm and thus displays desired photocatalytic properties for the full utilization of all solar energy, especially in the unexploited NIR part, which accounts for most of the sunlight. Encouraged by the above exciting photocatalytic outcome, we then go further to propose a plausible mechanism for interpreting the NIR-driven photocatalytic properties, which is based on the hypothesis of low-valent W⁵⁺ site induced free electrons and evidence-based ESR results.