A heteropentanuclear metal string complex [Mo<sub>2</sub>NiMo<sub>2</sub>(tpda)<sub>4</sub>(NCS)<sub>2</sub>] with two linearly aligned quadruply bonded Mo<sub>2</sub> units connected by a Ni ion and a meso configuration of the complex - Concepedia

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A heteropentanuclear metal string complex [Mo<sub>2</sub>NiMo<sub>2</sub>(tpda)<sub>4</sub>(NCS)<sub>2</sub>] with two linearly aligned quadruply bonded Mo<sub>2</sub> units connected by a Ni ion and a meso configuration of the complex

25

Citations

27

References

2016

Year

Wei‐Chieh Hung, Marc Sigrist, Shao‐An Hua, Lai‐Chin Wu, Tsai‐Jung Liu, Bih‐Yaw Jin, Gene‐Hsiang Lee, Shie‐Ming Peng

Chemical Communications

Abstract

A dimeric molybdenum precursor and nickel ions are used to synthesize a symmetric heteropentanuclear complex, [Mo<sub>2</sub>NiMo<sub>2</sub>(tpda)<sub>4</sub>(NCS)<sub>2</sub>]. This complex possesses unique structural features, as the four ligands are coordinated to the metal framework in a meso configuration. Furthermore, the central Ni<sup>2+</sup> ion is in a high spin state.

References

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