Tetsu-to-Hagane · 1991 · 11 citations · 1 references
EngineeringMaterials EngineeringMaterials ScienceMetallic MaterialsMetallurgyPhase TransformationsAlloysFerrous MetallurgyMetal FormingMetalsPhysical MetallurgySteel MaterialsAlloy Solidification BehaviorAlloyingIron-based AlloysMetallurgical CharacterizationMetallurgical Microstructure EffectsPhase Transformations In Iron AlloysPowder Metallurgy Of SteelSteel Metallurgy
The effects of various manufacturing conditions on powdering characteristics were investigated. Powdering is suppressed by an increase in Al content of the bath, a decrease in the bath temperature and a decrease in the galvannealing temperature. All of these conditions tend to delay the alloying progress. In the case of low Al content (0.12%), ζ-phase (FeZn13) abruptly, appears and forms homogeneous layer at the initial stage of alloying, and then completely changes into δ1-phase (FeZn7) in a short period. When the Al content is high (0.16%), the alloying progress is slow and ζ-phase appears heterogeneously at localized spots with time lags. The ζ-phase which appeared late remains unchanged up to the δ1-phase. As the hardness of ζ-phase is lower than that of δ1-phase, the ζ-phase deforms preferentially and relaxes a part of stress induced by forming, therefore powdering is suppressed.
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Max Hansen, K. Anderko, H. W. Salzberg · Journal of The Electrochemical Society · 1958 · 14.8K citations