Improved Electrochemical Performance of LiFePO₄@N-Doped Carbon Nanocomposites Using Polybenzoxazine as Nitrogen and Carbon Sources

Abstract

Polybenzoxazine is used as a novel carbon and nitrogen source for coating LiFePO₄ to obtain LiFePO₄@nitrogen-doped carbon (LFP@NC) nanocomposites. The nitrogen-doped graphene-like carbon that is in situ coated on nanometer-sized LiFePO₄ particles can effectively enhance the electrical conductivity and provide fast Li⁺ transport paths. When used as a cathode material for lithium-ion batteries, the LFP@NC nanocomposite (88.4 wt % of LiFePO₄) exhibits a favorable rate performance and stable cycling performance.