Concepedia

Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(<scp>iii</scp>)-catalyzed C–H activation

Natthawat Semakul, Kelvin E. Jackson, Robert S. Paton, Tomislav Rovis

Chemical Science · 2016 · 110 citations · 40 references

DOIFull text

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Concepts

Abstract

]dihydroisoquinolones with high diastereocontrol, which could then be easily transformed into synthetically useful building blocks for pharmaceuticals and bio-active molecules.

References

40

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

Tetsuya Satoh, Masahiro Miura · Chemistry - A European Journal · 2010 · 1.8K citations · Full text

, , +10

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

David Lapointe, Keith Fagnou · Chemistry Letters · 2010 · 1.1K citations

, , +9

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

Guoyong Song, Xingwei Li · Accounts of Chemical Research · 2015 · 978 citations

, , +14

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

Nicolas Guimond, Serge I. Gorelsky, Keith Fagnou · Journal of the American Chemical Society · 2011 · 931 citations

, , +17

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

Nicolas Guimond, Christina Gouliaras, Keith Fagnou · Journal of the American Chemical Society · 2010 · 769 citations

, , +17