In Situ Solid‐State Synthesis of a AgNi/g‐C₃N₄ Nanocomposite for Enhanced Photoelectrochemical and Photocatalytic Activity

Abstract

A graphitic carbon nitride (g-C₃ N₄ ) polymer matrix was embedded with AgNi alloy nanoparticles using a simple and direct in situ solid-state heat treatment method to develop a novel AgNi/g-C₃ N₄ photocatalyst. The characterization confirms that the AgNi alloy particles are homogeneously distributed throughout the g-C₃ N₄ matrix. The catalyst shows excellent photoelectrochemical activity for water splitting with a maximum photocurrent density of 1.2 mA cm^-2 , which is the highest reported for doped g-C₃ N₄ . Furthermore, a detailed experimental study of the photocatalytic degradation of Rhodamine B (RhB) dye using doped g-C₃ N₄ showed the highest reported degradation efficiency of approximately 95 % after 90 min. The electronic conductivity increased upon incorporation of AgNi alloy nanoparticles on g-C₃ N₄ and the material showed efficient charge carrier separation and transfer characteristics, which are responsible for the enhanced photoelectrochemical and photocatalytic performance under visible light.