Concepedia

Publication | Open Access

{[Ir<sub>3</sub>(cod)<sub>3</sub>(μ<sub>3</sub>-S)<sub>2</sub>](μ<sub>3</sub>-S)SnCl}<sub>2</sub> – a ternary Ir–Sn–S cluster with the iridium atoms in three different chemical environments

DOIFull Paper Access

11

Citations

52

References

2016

Year

Eliza Leusmann, Eugenie Geringer, Stefanie Dehnen
Dalton Transactions

Abstract

Reactions of Sn-S clusters with [IrCl(cod)]<sub>2</sub> afforded an Ir-Sn-S cluster with unprecedented topology, {[Ir<sub>3</sub>(cod)<sub>3</sub>(μ<sub>3</sub>-S)<sub>2</sub>](μ<sub>3</sub>-S)SnCl}<sub>2</sub>, in which two [Ir<sub>3</sub>S<sub>2</sub>] units and a central [Sn<sub>2</sub>S<sub>2</sub>] unit are connected via Ir-S and Ir-Sn bonds. Each of the crystallographically independent Ir atoms exhibits a specific chemical environment. Quantum chemical studies shed light on the electronic structure of the multinary cluster and the Ir-Sn bonds.

References

YearCitations

Page 1