In Operando XRD and TXM Study on the Metastable Structure Change of NaNi_1/3Fe_1/3Mn_1/3O₂ under Electrochemical Sodium‐Ion Intercalation

Abstract

In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi1/3Fe1/3Mn1/3O2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. An O3′ and P3′ monoclinic phase occur, and redox couples of Ni3+/Ni4+ and Fe3+/Fe4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.