Hierarchical silicalite-1 octahedra comprising highly-branched orthogonally-stacked nanoplates as efficient catalysts for vapor-phase Beckmann rearrangement

Albert M. Chang, Hsu-Ming Hsiao, Tsai-Hsiu Chen, Ming‐Wen Chu, Chia‐Min Yang

Chemical Communications · 2016 · 30 citations · 31 references

Concepts

Abstract

A triblock structure-directing agent was designed to synthesize hierarchical silicalite-1 octahedra comprising highly-branched, orthogonally-stacked and self-pillared nanoplates that exhibited excellent and stable activity for the vapor-phase Beckmann rearrangement of cyclic oximes and high lactam selectivity.

References

31